| Name | Seed Result | Station Number |
|---|
Iker Carrasco Ruiz | 7:00.31 | 1 | Carlos Pedro Casado de Achával | 17:10.00 | 2 | Sergio Chaparro Díaz-Cano | 20:16.00 | 3 | Jesús Lindo García | 28:40.00 | 4 | António Gomes | 32:42.00 | 5 | Vasco Vasconcelos | 45:10.00 | 6 | Manuel Prieto de Antón | | 8 | Ginneidy Camila León Zabala | | 10 | Laura Freitas Martín | | 9 | Pedro Azevedo | | 7 |